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However, cooperative increased binding of the 1a 3a co-sensitized device demonstrates that dye packing overrides any differences due to the presence of the small internal dipole.

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Electrochemical studies of the porphyrin–bridge–anchor dyes self-assembled on mesoporous nanoparticle Zr O films, show that the presence or direction of the bridge dipole does not have an observable effect on the electronic properties of the porphyrin ring.

Subsequent photovoltaic measurements of nanostructured Ti O semiconductor films in dye sensitized solar cells show a reduced photocurrent for photosensitizers 1a and 3a containing a bridge dipole.

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